Ultra-fast synthesis and thermodynamic analysis of MoAlB by self-propagating high-temperature combustion synthesis

نویسندگان

چکیده

MoAlB as a typical member of MAB phases has attracted much-growing attention due to its unique properties. However, the low production powders limits further development and potential applications. In present work, ultra-fast preparation high-purity in few seconds is achieved by self-propagating high-temperature synthesis (SHS) using raw powder mixture at an atomic ratio Mo : Al B = 1 1.3 1. SHS reaction mechanism obtained analyzing corresponding composition changes starting materials. Furthermore, thermodynamic prediction for consistent with experiments, where also conforms two common conditions SHS. The enthalpy vs. temperature curve shows that adiabatic decreases amount excuse increasing but increases when pre-heating reactants. Also, this calculation provides new idea other

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Synthesis of Al2O3-ZrO2 Nanocomposite by Mechanical Activated Self-propagating High Temperature Synthesis(MASHS) and Ignited via Laser

By consideration of unique properties of composite Al2O3-ZrO2 such as high toughness, high wear resistant and relative low thermal expansion, in this study, nanocomposite of Al2O3-ZrO2 was produced by Mechanical activated Self propagating High-temperature Synthesis (MASHS) using laser beam for ignition. First Al and ZrO2 powders were mixed in the mole ratio of 1:1 and milled for 1, 3 and 6 hour...

متن کامل

Self-propagating Combustion Synthesis via an Msr

9 The synthesis of (Ti1-xZrx)B2-Al2O3, (Ti1-xHfx)B2-Al2O3 and (Zr1-xHfx)B2-Al2O3 10 (x=0, 0.5 and 1) powder nanocomposites via a mechanochemical method using TiO2, ZrO2, 11 HfO2, HBO2 and Al as the raw materials was investigated. The formation of the 12 nanocomposites proceeds via a mechanically-induced self-sustaining reaction (MSR) process 13 that involves several simultaneous reactions. The ...

متن کامل

Self-propagating high-temperature synthesis for compound thermoelectrics and new criterion for combustion processing

The existing methods of synthesis of thermoelectric (TE) materials remain constrained to multi-step processes that are time and energy intensive. Here we demonstrate that essentially all compound thermoelectrics can be synthesized in a single-phase form at a minimal cost and on the timescale of seconds using a combustion process called self-propagating high-temperature synthesis. We illustrate ...

متن کامل

Burning Velocities in Catalytically Assisted Self-Propagating High-Temperature Combustion Synthesis Systems

The current work presents an experimental study of catalytically assisted self-propagating high-temperature synthesis (SHS) of the tantalum/carbon material system. The effects of controlled amounts of two gas-phase transport agents (carbon dioxide and vaporized iodine) were examined. The gas-phase transport agents resulted in burning velocities 2 to 4 times faster than burning velocities observ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Journal of Advanced Ceramics

سال: 2023

ISSN: ['2227-8508', '2226-4108']

DOI: https://doi.org/10.26599/jac.2023.9220680